The latices of poly(BA-co-MMA-co-AA) were prepared at a solid content of 50% by two-stage sequential emulsion polymerization, and this process consisted of a batch seed stage giving a particle diameter of 111 nm, which was then grown by the semicontinuous addition of monomers to final diameter of 303 nm. Dynamic light scattering (DLS) was used to monitor the particle diameters and proved that no new nucleation occurred during the growth stage. Copolymerization of BA with MMA raised the glass transition
temperature (T(g)) of the see more soft acrylic polymers, and had the effect of improving shear resistance, while the loop tack and peel adhesion kept relatively high. The relationship between pressure-sensitive properties and molecular parameters, such as gel content
and molecular weight, was evaluated. (C) 2011 Wiley Periodicals, Inc. J Appl Polym Sci 123: 1068-1078, 2012″
“We present a low-temperature micro-photoluminescence (mu-PL) study of ensembles of InAs/GaAs quantum dots (QDs) with respect to its circular polarization BI 6727 purchase (rho(c)) for a manifold of experimental conditions such as single or dual laser excitation, different excitation energies (h upsilon(ex)), varying excitation powers (P(ex)) of both lasers, and with or without an external magnetic field (B(ext)). It is demonstrated that an essential rho(c) (<= 40%) could be recorded depending on P(ex), even at B(ext) = 0 for h upsilon(ex) exceeding the PL energy of the wetting layer (E(WL)), while rho(c) remains negligible for h upsilon(ex) < THZ1 mw E(WL). To explain the data obtained, a model is developed according to which a nuclear magnetic field (B(N)) is created in the QDs by spin-polarized electrons. The B(N) plays a crucial role in the preservation of the electron spin, which otherwise effectively relaxes due to the presence of the anisotropic electron-hole exchange interaction
(omega(ex)). The application of an additional infra-red laser gives rise to a population of excess holes in the QDs, thus producing positively charged excitons. In this case, omega(ex) = 0 and accordingly, rho(c) approximate to 40% at B(ext) = 0 is recorded, even for excitation with h upsilon(ex) < E(WL). (C) 2011 American Institute of Physics. [doi:10.1063/1.3599853]“
“Nano carboxylic acrylonitrile butadiene rubber latex-toughened-phenolic resins (XNBRL-PF) were prepared by in situ polymerization in this work. The influence of nano XNBRL on the microstructure and physical properties of modified PF resin was investigated. Impact test testified that the impact strength of XNBRL-PF was remarkably improved compared to pure PF and as the content of XNBRL increased to 10 wt %, the impact strength of the XNBRL-PF kept increasing.