Typically, Luminespib OPV composes of electron acceptors (e.g., [6,6]-phenyl-C61 butyric acid methyl ester (PCBM)) and hole transport conjugated polymers

(e.g., poly(3-hexylthiophene (P3HT)) [8] as an 10058-F4 ic50 active layer in the OPV. Owing to relative low carrier mobility and a similar band offset of most inorganic materials to PCBM. PCBM is usually replaced by inorganic nanomaterials as electron acceptor in most hybrid solar cells. Up to date, various inorganic semiconductors have been studied, including ZnO [9], TiO2[10], CdSe [11], CdS [12], PbSe [13], and PbS [14]. Among them, metal sulfides or selenides (i.e., Cd and Pb) were extensively investigated. Examples have been reported by as Alivisatos et al., indicating P3HT/CdSe nanorod hybrid solar cells achieve a remarkable power-conversion efficiency (PCE) of 1.7% [11]. Xu et al. have demonstrated a solar PF-01367338 molecular weight cell based on P3HT/PbSe NCs hybrids with a PCE of 0.13% [13]. However, Cd and Pb are considered as hazard elements to environments, which limit the hybrid solar cell

systems as the commercialized product. In this study, we report a hybrid solar cell based on CIGS NCs with a conjugated polymer P3HT as matrix. Chalcopyrite series material CIGS is well known as a direct bandgap material with an intrinsic high optical absorbing coefficient. Such superior characteristic and IKBKE tunable optical energy gap engineering that matches well with the solar spectrum makes CIGS a promising PV material in the near future [15]. The blend ratios of CIGS NCs to P3HT, solvent effects on thin film morphologies, interface between P3HT/CIGS NCs and post-annealing of devices were investigated and the best performance of photovoltaic devices was measured. The approach combines non-toxic advantage of CIGS, benefitting a development in hybrid solar cells. Methods Synthesis of CIGS NCs CIGS nanocrystals with stoichiometric of CuIn0.5Ga0.5Se2 was synthesized

by chemical method. Oleylamine with 12 mL, 0.5 mmol of CuCl (0.0495 g), 0.25 mmol of InCl3 (0.0553 g), 0.25 mmol of GaCl3 (0.0440 g), and 1.0 mmol of elemental Se powder (0.0789 g) were mixed into a tri-neck beaker attached to the heating mantle. The beaker was purged by argon bubbling of oxygen and water at 130°C for 1 h. After purge, temperature was allowed to slowly increase to 265°C with slope of 2.3°C/min and held at 265°C for 1.5 h under vigorous stirring. The beaker was then cooled to room temperature by immersion into a cold water bath. The nanocrystals were extracted by a centrifugation process at 8,000 revolutions per minute (rpm) for 10 min by addition of 15 mL ethanol and 10 mL hexane.